LITHIUM INDIUM SELENIDE LiInSe2 (LISe)

Chemical formula: LiInSe2
Symmetry: Pna21
Density (g/cm3): 5.46
Mohs hardness: 4
Transparency range (μm): 0.46 – 14
Optical damage threshold (MW/cm2): 40 (1064 nm, 14 ns)
Refractive index: nx – 2.2977, ny – 2.3390, nz – 2.3486 (λ = 1.0 μm)
Nonlinear coefficients (pm/V): d31 = 11.78, d24 = 8.17 @2.3 μm
Surface quality: 30/20 (scratch/dig)
Flatness: λ/4 (546 nm)
Parallelism: < 40”

1. Isaenko L., Yelisseyev A., Lobanov S., Rotermund F., Petrov V., Slekys G., Zondy J.-J. A new ternary chalcogenide crystal for nonlinear optical applications in the mid-infrared: LiInSe2. CLEO, OSA Technical Digest (Optica Publishing Group, 2002), paper CFJ3
https://opg.optica.org/abstract.cfm?uri=cleo-2002-CFJ3

2. Isaenko L., Yelisseyev A., Lobanov S., Petrov V., Rotermund F., Slekys G., Zondy J.-J. LiInSe2: A biaxial ternary chalcogenide crystal for nonlinear optical application in the midinfrared. Journal of Applied Physics 91 (2002) 9475-9480
https://aip.scitation.org/doi/abs/10.1063/1.1478139

3. A.P. Yelisseyev, V.A. Drebushchak, A.S. Titov, L.I. Isaenko, S.I. Lobanov, K.M. Lyapunov, V.A. Gruzdev, S.G. Komarov, V. Petrov, J.-J. Zondy. Thermal properties of the mid-infrared nonlinear crystal LiInSe2. Journal of Applied Physics 96 (2004) 3659-3665
https://aip.scitation.org/doi/abs/10.1063/1.1784616

4. A.P. Yelisseyev, A.S. Titov, K.M. Lyapunov, V.A. Drebushchak, L.I. Isaenko, S.I. Lobanov. Thermal and thermo-optic parameters of LiInSe2 single crystals. Journal of Crystal Growth 275 (2004) e1679–e1684
https://www.sciencedirect.com/science/article/pii/S0022024804017300?via%3Dihub

5. L. Isaenko, I. Vasilyeva, A. Merkulov, A. Yelisseyev, S. Lobanov. Growth of new nonlinear crystals LiMX2 (M=Al, In, Ga; X=S, Se, Te) for the mid-IR optics. Journal of Crystal Growth 275 (2005) 217–223
https://www.sciencedirect.com/science/article/pii/S0022024804014034

6. V. Vedenyapin, A Yelisseyev, S. Lobanov, L. Isaenko, V.Petrov, J-J. Zondy. LiInSe2 nanosecond optical parametric oscillator. Optics Letters 30 (2005) 2460-2462
https://opg.optica.org/ol/abstract.cfm?uri=ol-30-18-2460

7. J.-J. Zondy, V. Vedenyapin, A. Yelisseyev, S. Lobanov, L. Isaenko, V. Petrov. LiInSe2 nanosecond optical parametric oscillator. Optics Letters 30 (2005) 2460-2462
https://opg.optica.org/ol/abstract.cfm?uri=ol-30-18-2460

8. L. Isaenko, A.Yelisseyev, S. Lobanov, P. Krinitsin, V. Petrov, J.-J. Zondy. Ternary chalcogenides LiBC2 (B = In, Ga; C= S, Se, Te) for mid-IR nonlinear optics. Journal of Non-Crystalline Solids 353 (2006) 2439-2443
https://www.sciencedirect.com/science/article/abs/pii/S0022309306005187?via%3Dihub

9. J-J. Zondy, V. Petrov, A. Yelisseyev, L. Isaenko, S. Lobanov. “Orthorhombic crystals of lithium thioindate and selenoindate for nonlinear optics in the mid-IR” ” in Springer -Verlag Book “Mid-Infrared Coherent Sources and Application” 2007, Springer, Series B: Physics and Biophysics, Eds.: Majid Ebrahimzadeh and Irina Sorokina, pp. 67-104.

10. G. Marchev, A. Tyazhev, V. Vedenyapin, D. Kolker, A. Yelisseyev, S. Lobanov, L. Isaenko, J-J. Zondy, V. Petrov, Nd:YAG pumped nanosecond optical parametric oscillator based on LiInSe2 with tenability extending from 4.7 to 8.7 um. OPTICS EXPRESS 17 (2009) 13441-13446
https://opg.optica.org/oe/fulltext.cfm?uri=oe-17-16-13441&id=183739

11. G. Marchev, A. Tyazhev, V. Vedenyapin, D. Kolker, A. Yelisseyev, S. Lobanov, L. Isaenko, J-J. Zondy, V. Petrov. Broadly tunable LiInSe2 optical parametric oscillator pumped by a Nd:YAG laser. Proc. of SPIE 7487 (2009) 74870F-1-74870F-9
https://doi.org/10.1117/12.830238

12. Valentin Petrov, Jean-Jacques Zondy, Olivier Bidault, Ludmila Isaenko, Vitaliy Vedenyapin, Alexander Yelisseyev, Weidong Chen, Aleksey Tyazhev, Sergei Lobanov, Georgi Marchev, Dmitri Kolker. Optical, thermal, electrical, damage, and phase-matching properties of lithium selenoindate. JOSA B 27 (2010) 1902-1927
https://opg.optica.org/josab/abstract.cfm?uri=josab-27-9-1902

13. M. Beutler, I. Rimke, E. Buttner, V. Petrov, L. Isaenko. Difference-frequency generation of fs and ps mid-IR pulses in LiInSe2 based on Yb-fiber laser pump sources. OPTICS LETTERS 39 (2014) 4353-4355
https://opg.optica.org/ol/abstract.cfm?uri=ol-39-15-4353

14. I.G. Vasilyeva, A.A. Pochtar, L.I. Isaenko. Origin of solid solution in the LiInSe2-In2Se3 system. Journal of Solid State Chemistry 220 (2014) 91-96
https://www.sciencedirect.com/science/article/abs/pii/S0022459614003612

15. L.I. Isaenko, A.P. Yelisseyev. Recent study of nonlinear crystals for the mid IR. Semiconductor Science and Technology 31 (2016) 123001
http://dx.doi.org/10.1088/0268-1242/31/12/123001

16. Valeri A. Drebushchak, Ludmila I. Isaenko, Sergey I. Lobanov, Pavel G. Krinitsin, Sergey A. Grazhdannikov. Experimental heat capacity of LiInS2, LiInSe2, LiGaS2, LiGaSe2 and LiGaTe2 from 180 to 460 K. Journal of Thermal Analysis and Calorimetry 129 (2017) 103-108
https://link.springer.com/article/10.1007/s10973-017-6176-9

17. K. Siemek, A.P. Yelisseyev, P. Horodek, S.I. Lobanov, A.A. Goloshumova, A.V. Belushkin, L.I. Isaenko. Optical and positron annihilation studies of structural defects in LiInSe2 single crystals. Optical Materials 109 (2020) 110262
https://doi.org/10.1016/j.optmat.2020.110262

18. A.V. Belushkin, A.A. Bogdzel, A.A. Goloshumova, L.I. Isaenko, S.I. Lobanov, V.M. Milkov, A.Yu. Tarasova, A.P. Yelisseyev. Study of LiInSe2 Single Crystals for the Thermal Neutron Detection. Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques 14 (2020) S15–S18
https://link.springer.com/article/10.1134/S102745102007006X

19. O. Daulbaev, L. I. Isaenko, A. A. Bogdzel’, S. I. Lobanov, P. G. Krinitsyn, V. M. Milkov, A. V. Belushkin. Comparative Study of LiInSe2 Single Crystals for Thermal-Neutron Detection. Crystallography Reports 67 (2022) 464–469
https://link.springer.com/article/10.1134/S1063774522030063

20. Victor V. Atuchin, Ludmila I. Isaenko, Sergei I. Lobanov, Alina A. Goloshumova, Maxim S. Molokeev, Zhaoming Zhang, Zhang Xingyu, Xingxing Jiang, Zheshuai Lin. Anisotropic thermal expansion and electronic structure of LiInSe2. Molecules 27 (2022) 5078
https://doi.org/10.3390/molecules27165078

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